Atmospheric Oxidation of Ethers Under High and Low NOx Conditions

نویسندگان

  • J. Wenger
  • E. Collins
  • H. Sidebottom
  • S. Le Calvé
  • A. Mellouki
  • G. Le Bras
  • K. Wirtz
چکیده

The photooxidation of diethyl ether (C2H5OC2H5) and diisopropyl ether, (CH3)2CHOCH(CH3)2, in the presence of NOx was studied at the European Photoreactor (EUPHORE) in May 1998. The main objective of the experiments was to validate the degradation mechanisms that are based on data obtained from laboratory photoreactor studies. For diisopropyl ether, the experiments provided product yield data that differed significantly from that obtained in conventional photoreactor studies. In order to elucidate further mechanistic information, the photooxidation of diisopropyl ether was studied again in July 1998 in the presence and absence of NOx.

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تاریخ انتشار 1999